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Simon Difford’s Avatar Simon Difford
27th June at 06:23
It may be just “exponential kinetics”, but the maths and science in the links are unfathomable. Are you saying that in the process of making a rich sugar syrup, even with prolonged boiling, there will be NO conversion to glucose and fructose? Or just minimal conversion?
I D’s Avatar I D
7th July at 09:37
Hi - I found this link on the sugar association website regarding production of sucrose from sugar cane:

https://www.sugar.org/blog/refining-and-processing-sugar-cane/

See step 3 - boiling sugar solution to thicken it. If boiling sucrose without an acid catalyst (or presence of an enzyme) did indeed cause sucrose to convert to glucose and fructose, then the sugar industry would have to find another way to produce sugar. Hope that helps.
I D’s Avatar I D
4th July at 12:00
from the second link:

"The lower-right datapoint is very close to 100 °C, and shows the first-order rate constant for sucrose hydrolysis is about 10(exp−6) per second. That means that 63% degradation would take 10(exp6) seconds, or about 11.5 days. Getting 99% degradation would take about 53 days."

In layman's terms, heating a mixture of refined (white) sugar in clean water, hot enough & long enough (a few minutes on a moderate heat setting - there's no need for prolonged boiling) to disolve the sugar and form a rich syrup is going to lead to negligible conversion to glucose and fructose. Certainly nothing you'd notice outside of a laboratory.

I doubt anyone is going to feel the need to boil sugar syrup for long enough (ie days) at home to see the effect. Also, without technical equipment (eg a condenser) doing so would tend to drive off water (affecting the concentration & hence viscocity) and start to caramelise the sugar (affecting colour taste) - which is fine if we are making caramel or toffee. I just tested this in my kitchen, that's exactly what happened.
Simon Difford’s Avatar Simon Difford
7th July at 10:41
I believe it's still beneficial to only use the little heat necessary to help dissolve the sugar, so I have amended point 5 to also include the points you make. Many thanks.