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Made with Bozal Cenizo and garnished with expressed orange peel. Good as is, but for experimentation, will try bumping up the mezcal .25 oz and add chocolate bitters as suggested in other comments.
A pretty interesting cocktail - upon tasting, I couldn't shake that this is a mezcal Last Word/Closing Argument without the citrus, leaning towards the profile of an Old Fashioned-style of drink. I'd fully expect that as a template, you can experiment with just about any amaro out there to substitute the Lucano to create vastly different drinks. I also do agree that 1 dash of any bitters probably helps this cocktail out a lot if a more delicate amaro is chosen.
On a second round, I attempted the recipe with Amaro Nonino to replace the same amount of Lucano, and added a single dash of chocolate bitters as Paul Green below had suggested - quite enjoyable!
Montenegro is a very different animal, and while closer, Averna is different again. To properly experience you'll need to invest in a bottle of Lucano.
Wanted to follow up by saying the drink came out fantastic. Thank you Diffords for the cocktail suggestion! I’ve been looking for a variation of the M&M and I wouldn’t have thought to add Luxardo maraschino liqueur. For anyone interested in Doc Hersons amaro, it’s wonderful: https://www.newyorkcraftspirits.com/products/doc-hersons-bitter-liqueur